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Chapter 22 Chemicals from crude oil
 
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1.

Crude oil and its products

  • Crude oil is a fossil fuel like coal and natural gas.
  • Crude oil contains a mixture of hundreds of carbon compounds.
  • Most of the compounds in crude oil are hydrocarbons – compounds containing only hydrogen and carbon.
  • The hydrocarbons in crude oil can be separated into fractions by fractional distillation.
  • The boiling points and other properties of these fractions differ and as a result they have different uses.
  • Cracking is used to produce additional qualities of petrol from the heavier fractions of crude oil. During cracking, larger alkane molecules are split into smaller alkanes plus alkenes using a catalyst at high temperature.

2.

Hydrocarbons – alkanes and alkenes

  • Hydrocarbons are typical simple molecular compounds.
    – They have low melting points and low boiling points.
    – They are insoluble in water.
  • Alkanes are the simplest hydrocarbons.
  • The alkanes form a homologous series of compounds with similar properties in which the formulas differ by For example, methane ethane and propane etc.
  • Alkanes have strong bonds so they have few reactions.
    They do, however, combine with reactive non-metals like oxygen and chlorine.


  • Hydrocarons, like ethane and other alkanes which have four single covalent bonds to all their carbon atoms, are described as saturated compounds.
  • Hydrocarbons, like ethene, which contain a carbon-carbon double bond
    are called alkenes.


  • Hydrocarbons, like ethene and other alkenes, which have double bonds between some carbon atoms are described as unsaturated compounds.
3.

From alkenes to polymers
Weathering is the breaking up of rocks. There are two kinds of weathering.

  • Alkenes are much more reactive than alkanes because of their reactive double bonds. These reactive double bonds allow alkenes to undergo addition reactions.
  • Alkenes, like ethene, decolorise yellow/orange bromine water. This reaction is a simple addition reaction. It is used as a test for alkenes and to distinguish between alkanes and alkenes.


  • Small alkene molecules, like ethene, can add to each other to form a giant
    molecule. This process is called addition polymerisation.


  • The giant molecule is called a polymer.
  • The small molecules, like ethene, which add to each other are called
    monomers.
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